久久国产精品午夜一区_91精品國產高清久久久久久91_?级毛片免费全部播放_欧美色图在线视频一区二区三区_国产综合亚洲一区二区三区_中文字幕熟女网_国产精品男人爽免费视频_九九无码网战_亚洲日本三级电影在线观看_欧美日韩DVD手机在线不卡

 

文獻名：Effect of Toluene Addition in an Electric Arc on Morphology, Surface Modification, and Oxidation Behavior of Carbon Nanohorns and Their Sedimentation in Water

 

 

作者： Kseniya I. Baskakova, Olga V. Sedelnikova *, Evgeniy A. Maksimovskiy, Igor P. Asanov , Aida T. Arymbaeva, Lyubov G. Bulusheva and Alexander V. Okotrub *

Nikolaev Institute of Inorganic Chemistry, Siberian Branch, Russian Academy of Sciences, 630090 Novosibirsk, Russia

 

摘要：Carbon nanohorns (CNHs) are attractive for various applications, where a high specific surface area and long dispersion stability in water are important. In the present work, we study these parameters of CNHs prepared by arc evaporation of graphite depending on the conditions of the synthesis and subsequent oxidation in air. It is shown that the addition of toluene in the reactor during the arcing allows obtaining CNHs functionalized with −CH_x groups. Heating of CNHs in air at 400 °C leads to substitution of −CH_x groups for oxygen-containing groups. Moreover, the CNH endcaps are opened at 500 °C, and as a result, the specific surface area of CNHs increases 4 times. Aqueous suspensions with a concentration of oxidized CNHs of 100 µg/mL are stable for 8 months.

 

關鍵詞：carbon nanohorns; oxidation; specific surface area; aqueous suspension; optical absorption